Synthesis of random copolymers of 4-vinylpyridine with n-octadecyl acrylate/n-octadecyl methacrylate by metal-free ATRP
Abstract
Poly(4-vinylpyridine-r-n-octadecyl acrylate) and poly(4-vinylpyridine-r-n-octadecyl methacrylate) were successfully synthesised via atom transfer radical polymerization (ATRP) using 10-phenylphenothiazine as the photo-induced catalyst. The resulting copolymers were structurally characterised by proton nuclear magnetic resonance (1H NMR) and the interactions were analysed by Fourier-transform infrared (FTIR) spectroscopy.
Keywords:
ATRP, metal-free, n-octadecyl, pyridineDOI:
https://doi.org/10.31276/VJSTE.62(1).28-31Classification number
2.2
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Published
Received 20 January 2020; accepted 3 March 2020